TY - JOUR
T1 - Effects of anion concentration on ion-transport pressure in nanopores
AU - KIM, Taewan
AU - LU, Weiyi
AU - HAN, Aijie
AU - PUNYAMURTULA, Venkata K.
AU - CHEN, Xi
AU - QIAO, Yu
N1 - This study was supported by The National Science Foundation and The Sandia National Laboratory under Grant No. CMS-0623973.
PY - 2009/1/5
Y1 - 2009/1/5
N2 - In an experiment on pressure-driven ion transport in nanopores of a zeolite, the anion concentration is varied in a broad range. As the anion concentration is relatively low, its influence on the ion transport pressure, which reflects the system free energy variation rate, is negligible. When the anion concentration is relatively high, it has a pronounced effect on the ion transport pressure, which should be attributed to the unique surface ion structure in the confining nanoenvironment. The testing data also indicate that the effective interfacial tension is highly dependent on the anion size. © 2009 American Institute of Physics.
AB - In an experiment on pressure-driven ion transport in nanopores of a zeolite, the anion concentration is varied in a broad range. As the anion concentration is relatively low, its influence on the ion transport pressure, which reflects the system free energy variation rate, is negligible. When the anion concentration is relatively high, it has a pronounced effect on the ion transport pressure, which should be attributed to the unique surface ion structure in the confining nanoenvironment. The testing data also indicate that the effective interfacial tension is highly dependent on the anion size. © 2009 American Institute of Physics.
UR - http://www.scopus.com/inward/record.url?scp=58149528192&partnerID=8YFLogxK
U2 - 10.1063/1.3023071
DO - 10.1063/1.3023071
M3 - Journal Article (refereed)
SN - 0003-6951
VL - 94
JO - Applied Physics Letters
JF - Applied Physics Letters
IS - 1
M1 - 13105
ER -