Abstract
In the past, electrowetting was usually analyzed on large solid surfaces. In the current study, the effective solid-liquid interfacial tension in a nanoporous silica, which is measured by the ion transport pressure, is investigated experimentally. The interfacial tension decreases as the applied potential difference increases, while the magnitude of variation is much smaller than its bulk counterpart. The effect of the external electric field is saturated at a relatively low voltage. These unique phenomena can be attributed to the confinement effect of nanopore walls. © 2009 American Chemical Society.
Original language | English |
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Pages (from-to) | 9463-9466 |
Number of pages | 4 |
Journal | Langmuir |
Volume | 25 |
Issue number | 16 |
Early online date | 3 Jun 2009 |
DOIs | |
Publication status | Published - 18 Aug 2009 |
Externally published | Yes |
Bibliographical note
Special thanks are also due to Mr. L. A. Operhall for the help with the design of the experimental setup.Funding
This study was supported by the National Science Foundation and The Sandia National Laboratory under Grant No. CMMI-0705142, and the William J. von Liebigg Foundation.