Abstract
This article presents a tandem hydrogel-phase change material (PCM)-thermoelectric generator (TEG) structure for evaporation-driven cold energy storage and electricity harvesting. The hydrogel layer facilitates water evaporation under ambient conditions, generating a cooling effect that produces “cold energy”. This energy is stored in a PCM layer as latent energy, maintaining a stable temperature gradient without volume changes or leakage. The integrated TEG converts this gradient into electricity during both charging (evaporation-induced cooling and PCM solidification) and discharging (PCM melting and heat release) phases, enabling dual-phase power generation. Experimental results demonstrate a maximum power output of 1.6 mW and a power density of 100 μW/cm2 at ambient condition without energy input. In addition, we demonstrate an average power output of 0.3 mW and a power density of 19 μW/cm2 for a fully charged PCM under ambient conditions, with a cooling efficiency that reduces surface temperatures of TEG by up to 5°C. This article represents the first demonstration of simultaneous storage and utilization of evaporation thermal energy for electricity generation. This innovative design combines evaporative cooling, latent energy storage, and thermoelectric conversion, advancing sustainable energy solutions for low-grade heat environments and efficiently powering portable electronics.
| Original language | English |
|---|---|
| Article number | e202500635 |
| Number of pages | 8 |
| Journal | Small Structures |
| Volume | 7 |
| Issue number | 1 |
| Early online date | 12 Jan 2026 |
| DOIs | |
| Publication status | Published - Jan 2026 |
Bibliographical note
Publisher Copyright:© 2025 The Author(s). Small Structures published by Wiley-VCH GmbH.
Funding
This work was supported by the Shun Hing Institute of Advanced Engineering (#RNE‐p3‐24), Chinese University of Hong Kong (4055224), National Research Foundation Singapore (U2411D4011), Agency for Science, Technology and Research (R22I1IR053), and National Research Council of Thailand (B48G660114). Z. Gong is acknowledged for his help with PVA hydrogel preparation. This research is supported in part by project #RNE‐p3−24 of the Shun Hing Institute of Advanced Engineering, The Chinese University of Hong Kong. A.S. also acknowledges funding from CUHK Direct Grant 4055224, and startup funding from The Chinese University of Hong Kong. J.C. acknowledges funding from e‐Asia Joint Research Program award no. R22I1IR053, and LCER Phase 2 ETGC award no. U2411D4011. T. S. and S. R. acknowledge the NSRF via the Program Management Unit for Human Resources & Institutional Development, Research and Innovation (grant no. B48G660114). This research is also funded by the Vietnam National University, Ho Chi Minh City (Grant No. NCM2024‐50‐01).
Keywords
- energy harvesting
- energy storage
- evapolectrics
- hydrogels
- phase change materials
- thermoelectrics
- water evaporation