Abstract
Conventional thermoelectric materials have limited capability of scavenging electrical energy from low-grade heat (LGH). Based on the capacitive effect of liquid-solid interface in a nanoconfinement, we investigate a novel energy harvesting mechanism which is based on the thermally sensitive ion/charge distribution of electrolytes confined in nanopores. The mechanism is elucidated using comprehensive molecular dynamics (MD) simulations. The effective thermal sensitivity, effective figure of merit, and thermal-to-electric energy conversion efficiency of the nanofluidic system compare favorably with respect to the conventional thermoelectric materials. The result of a preliminary thermal-to-electrical energy conversion experiment on a nanoporous carbon is presented, to qualitatively show the feasibility of the approach.
Original language | English |
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Pages (from-to) | 805-811 |
Number of pages | 7 |
Journal | Nano Energy |
Volume | 1 |
Issue number | 6 |
DOIs | |
Publication status | Published - Nov 2012 |
Externally published | Yes |
Funding
The work is supported by National Natural Science Foundation of China ( 11172231 ), Changjiang Scholar Program from Ministry of Education of China, World Class University program through the National Research Foundation of Korea ( R32-2008-000–20042-0 ), DARPA ( W91CRB-11-C-0112 ), and National Science Foundation ( CMMI-0643726 and ECCS-1028010 ).
Keywords
- Conversion efficiency
- Electrical potential
- Energy harvesting
- Low-grade heat
- Nanofluids