Superior CO₂ uptake and enhanced compressive strength for carbonation curing of cement-based materials via flue gas

Carbonation curing of cement-based materials is an important pathway for CO₂ utilization and sequestration. Most previous studies focused on pure CO₂ carbonation curing. In this work, we demonstrate superior CO₂ uptake and enhanced compressive strength with flue gas (20% CO₂ concentration) carbonation curing. The flue gas carbonation rate is smaller at the beginning of curing, but the CO₂ uptake and compressive strength are larger than that of pure CO₂ curing at 12 h carbonation. Moreover, the growth rate of the post hydration strength is inversely proportional to the CO₂ uptake, but under proper combination of carbonation and hydration curing, the 28d strength of the flue gas carbonated specimen can be higher than that of the hydration specimen. The carbonation curing mechanism for the flue gas and pure CO2 is discussed from a microscopic perspective. The higher carbonation capacity of lower concentration CO₂ in cement carbonation curing may inspire new pathways in carbonation management. © 2022 Elsevier Ltd